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Beilstein J. Org. Chem. 2015, 11, 1155–1162, doi:10.3762/bjoc.11.130
Graphical Abstract
Scheme 1: Cinnamates bearing a nitroxyl moiety 5a–i from 4-acryloyloxy-2,2,6,6-tetramethylpiperidine-1-oxyl (3...
Figure 1: Conformations of the substituent in 2-position of the cinnamates 5e, 5h, 5i.
Scheme 2: The formation of the fragment ions at m/z 154, 124, 109.
Beilstein J. Org. Chem. 2012, 8, 1515–1522, doi:10.3762/bjoc.8.171
Scheme 1: MBH adducts 5a–o from 4-acryloyloxy-2,2,6,6-tetramethylpiperidine-1-oxyl.